Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, Volume 35Ernst Schaumann Thieme, 2000 - 850 pages Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy.
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Contents
Introduction | 1 |
E Schaumann | 15 |
Reactions with Molecular Chlorine | 39 |
Copyright | |
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Common terms and phrases
Abstr acetic acid AcOH added addition affords alcohols aliphatic alkanes alkenes alkyl allylic Allylic Chlorides Angew anhyd aqueous Ar¹ atom aziridines benzene bond Br₂ bromine bromoalkanes carbon catalyst CAUTION CCl4 CH₂Cl₂ Chem chloroalkanes chloromethyl Cl₂ CO₂H CO₂Me compounds conversion cooled cyclohexene DBPO Dibenzoyl peroxide distilled dried MgSO4 dried Na₂SO4 dropwise epoxides equiv esters Et₂O ether extracted filtrate flask formation give haloalkanes heating Houben-Weyl hydrogen bromide hydrogen chloride iodide iodine iodoalkanes MeCN Method methyl mixture was stirred mmol N-bromosuccinimide N₂ nucleophilic obtained organic layer oxide Perkin Trans peroxide Ph Ph presence propargylic R¹ R2 radical react reaction reactivity reagent reduced pressure reflux regioselectivity residue ring opening silica gel sodium soln solvent was removed substitution substrates sulfuryl chloride Synth temperature tert-butyl tertiary Tetrahedron Lett thionyl chloride tion Torr toxic triphenylphosphine Typical Variation yield Scheme